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Piston wetting can be isolated from the other sources of HC emissions from DISI engines by operating the engine predominantly on a gaseous fuel and using an injector probe to impact a small amount of liquid fuel on the piston top. This results in a marked increase in HC emissions. All of our prior tests with the injector probe used California Phase 2 reformulated gasoline as the liquid fuel. In the present study, a variety of pure liquid hydrocarbon fuels are used to examine the influence of fuel volatility and structure. Additionally, the exhaust hydrocarbons are speciated to differentiate between the emissions resulting from the gaseous fuel and those resulting from the liquid fuel. It is shown that the HC emissions correspond to the Leidenfrost effect: fuels with very low boiling points yield high HCs and those with a boiling point near or above the piston temperature produce much lower HCs.

An optical access engine was used to image the liquid film evaporation off the piston of a simulated direct injected gasoline engine. A directional injector probe was used to inject liquid fuel (gasoline, i-octane and n-pentane) directly onto the piston of an engine primarily fueled on propane. The engine was run at idle conditions (750 RPM and closed throttle) and at the Ford World Wide Mapping Point (1500 RPM and 262 kPa BMEP). Mie scattering images show the liquid exiting the injector probe as a stream and directly impacting the piston top. Schlieren imaging was used to show the fuel vaporizing off the piston top late in the expansion stroke and during the exhaust stroke. Previous emissions tests showed that the presence of liquid fuel on in-cylinder surfaces increases engine-out hydrocarbon emissions.

The effects of fuel properties on the emissions of a production vehicle with a gasoline direct injection engine operating over the Federal Test Procedure (FTP) cycle were investigated. The vehicle used was a 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine. Engine-out and tailpipe FTP emissions for six fuels and a California Phase 2 RFG reference fuel are presented. Four of the test fuels were blended from refinery components to meet specified distillation profiles. The remaining test fuels were iso-octane and toluene, an iso-alkane and an aromatic with essentially the same boiling point (at atmospheric pressure) that is near the T50 point for the blended fuels. Statistically significant effects, at the 95% confidence level, of the fuels on tailpipe emissions were found. Correlations were sought between the properties of the five blends and the Emissions Indices for engine-out hydrocarbons and NOx and for tailpipe particulates.

A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested at constant engine speed (2000 rpm) over a range of loads. Engine-out and tailpipe emissions of gas phase species were measured each second. This allowed examination of the engine-out emissions for late and early injection. Seven fuels were used for these tests: five blended fuels and two pure hydrocarbon fuels. These seven fuels can be divided into groups for examination of the effects of volatility, MTBE, and structure (an aromatic versus an i-alkane). Correlations between the fuel properties and their effects on emissions are presented. Use of steady state tests rather than driving cycles to examine fuel effects on emissions eliminates the complications resulting from accelerations, decelerations, and changes of injection timing but care had to be taken to account for the periodic regenerations of the lean NOx trap/catalyst.

The effect of the in-cylinder bulk flow on fuel distributions in the cylinder of a motored direct-injection S.I. engine was measured. Five different bulk flows were induced through combinations of shrouded and unshrouded valves, and port deactivation: stock, high tumble, reverse tumble, swirl, and swirl/tumble. Planar Mie scattering was used to observe the fuel spray movement in the centerline plane of a transparent cylinder engine. A fiber optic instrumented spark plug was used to measure the resulting cycle-resolved equivalence ratio in the vicinity of the spark plug. The four-valve engine had the injector located on the cylinder axis; the fiber optic probe was located between the intake valves. Injection timings of 90, 180, and 270 degrees after TDC were examined. Measurements were made at 750 and 1500 rpm with certification gasoline at open throttle conditions. From the images it was found that the type and strength of the bulk flow greatly affected the spray behavior.

The University of Texas Ethanol Vehicle Challenge team focused upon cold start/driveability, fuel economy, and emissions reduction for our 1999 Ethanol Vehicle Challenge entry. We replaced or coated all fuel system components that were not ethanol compatible. We used the stock PCM for all control functions except control of a novel cold-start system our team designed. The primary modifications for improved emissions control involved ceramic coating of the exhaust manifolds, use of close-coupled ethanol-specific catalysts, increased EGR for the operating conditions of the five longest cruises on the FTP, and our cold-start system that eliminates the need to overfuel the engine at the beginning of the FTP. This EGR control scheme should also benefit urban fuel economy. Additionally, we eliminated EGR at high load to improve power density.

A recently developed in-cylinder fuel injection probe was used to deposit a small amount of liquid fuel on various surfaces within the combustion chamber of a 4-valve engine that was operating predominately on liquefied petroleum gas (LPG). A fast flame ionization detector (FFID) was used to examine the engine-out emissions of unburned and partially-burned hydrocarbons (HCs). Injector shut-off was used to examine the rate of liquid fuel evaporation. The purpose of these experiments was to provide insights into the HC formation mechanism due to in-cylinder wall wetting. The variables investigated were the effects of engine operating conditions, coolant temperature, in-cylinder wetting location, and the amount of liquid wall wetting. The results of the steady state tests show that in-cylinder wall wetting is an important source of HC emissions both at idle and at a part load, cruise-type condition. The effects of wetting location present the same trend for idle and part load conditions.

A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested at constant engine speed (2000 rpm) over a range of loads. Engine-out and tailpipe emissions of gas phase species were measured each second. This allowed examination of the engine-out emissions for late and early injection. Regeneration of the lean NOx trap/catalyst was also examined, as was the efficiency of NOx reduction. NOx stored in the trap/catalyst is released at the leading edge of regenerations, such that the tailpipe NOx is higher than the engine-out NOx for a brief period. The efficiency of NOx reduction was <50% for the lowest loads examined. As the load increased, the efficiency of NOx reduction decreased to near 0% due to excessive catalyst temperatures. Loads sufficiently high to require a rich mixture produce high NOx reduction efficiencies, but in this case the NOx reduction occurs via the three-way catalysts on this vehicle.

A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested via a variety of driving cycles using California Phase 2 reformulated gasoline. A comparable PFI vehicle was also evaluated. The standard driving cycles examined were the Federal Test Procedure (FTP), Highway Fuel Economy Test, US06, simulated SC03, Japanese 10-15, New York City Cycle, and European ECE+EDU. Engine-out and tailpipe emissions of gas phase species were measured each second. Hydrocarbon speciations were performed for each phase of the FTP for both the engine-out and tailpipe emissions. Tailpipe particulate mass emissions were also measured. The results are analyzed to identify the emissions challenges facing the DISI engine and the factors that contribute to the particulates, NOx, and hydrocarbon emissions problems of the DISI engine.

The mixture preparation process was investigated in a direct-injected, 4-valve, SI engine under motored conditions. The engine had a transparent cylinder liner that allowed the fuel spray to be imaged using laser sheet Mie scattering. A fiber optic probe was used to measure the vapor phase fuel concentration history at the spark plug location between the two intake valves. The fuel injector was located on the cylinder axis. Two flow fields were examined; the stock configuration (tumble index 1.4) and a high tumble (tumble index 3.4) case created using shrouded intake valves. The fuel spray was visualized with the engine motored at 750 and 1500 RPM. Start of injection timings of 90°, 180° and 270° after TDC of intake were examined. The imaging showed that the fuel jet is greatly distorted for the high tumble condition, particularly at higher engine speeds. The tumble was large enough to cause significant cylinder wall wetting under the exhaust valves for some conditions.

The effect of combustion chamber wall-wetting on the emissions of unburned and partially-burned hydrocarbons (HCs) from gasoline-fueled SI engines was investigated experimentally. A spark-plug mounted directional injection probe was developed to study the fate of liquid fuel which impinges on different surfaces of the combustion chamber, and to quantify its contribution to the HC emissions from direct-injected (DI) and port-fuel injected (PFI) engines. With this probe, a controlled amount of liquid fuel was deposited on a given location within the combustion chamber at a desired crank angle while the engine was operated on pre-mixed LPG. Thus, with this technique, the HC emissions due to in-cylinder wall wetting were studied independently of all other HC sources. Results from these tests show that the location where liquid fuel impinges on the combustion chamber has a very important effect on the resulting HC emissions.

The Texas Project was a multi-year study of aftermarket conversions of a variety of light-duty vehicles to CNG or LPG. One aspect of this project was to examine the factors that influence the economics of fleet conversions to these alternative fuels. The present analysis did not include longer-term effects (such as possible increases in exhaust system life or increases in tire wear). Additionally, assumptions were required to estimate the costs of repairs to the alternative fuel system and engine. Other factors considered include conversion cost, fuel prices, annual alternative fuel tax (as applied for the state of Texas), annual miles accumulated, and the percent miles traveled while using the alternative fuel for dual fuel conversions.

A liquid-phase port injection system for liquefied petroleum gas (LPG) generally consists of a fuel storage tank with extended capability of operating up to 600 psi, a fuel pump, and suitable fuel lines to and from the LPG fuel injectors mounted in the fuel rail manifold. Port injection of LPG in the liquid phase is attractive due to engine emissions and performance benefits. However, maintaining the LPG in the liquid phase at under-hood conditions and re-starting after hot soak can be difficult. Multiphase behavior within a liquid-phase LPG injection system was investigated computationally and experimentally. A commercial chemical equilibrium code (ASPEN PLUS™) was used to model various LPG compositions under operating conditions.

The mixture preparation process was investigated in a direct-injected, 4-valve, SI engine under motored conditions. The interaction between the high-pressure fuel jet and the intake air-flow was observed. Laser-sheet droplet imaging was used to visualize the in-cylinder droplet distributions, and a single-component LDV system was used to measure in-cylinder velocities. The fuel spray was visualized with the engine motored at 1500 and 750 rpm, and with the engine stopped. It was observed that the shape of the fuel spray was distorted by the in-cylinder air motion generated by the intake air flow, and that this effect became more pronounced with increasing engine speed. Velocity measurements were made at five locations on the symmetry plane of the cylinder, with the engine motored at 750 rpm. Comparison of these measurements with, and without, injection revealed that the in-cylinder charge motion was significantly altered by the injection event.

Condensation of fuel vapor on the cold surfaces within the combustion chamber is investigated as a possible mechanism for increased HC emissions from SI engines during cold start. A one-dimensional, transient, mass diffusion analysis is used to examine the condensation of single-species fuels on the surfaces of the combustion chamber as the pressure within the cylinder rises during compression and combustion, and re-vaporization during expansion, blowdown, and exhaust. The effects of wall temperature, fuel volatility, and engine load and speed on this mechanism are also discussed. This analysis shows that low-volatility fuel components can condense on the surfaces of the combustion chamber when the surface temperatures are sufficiently low. This condensed fuel may re-vaporize during the power and exhaust strokes, or it may remain in the combustion chamber until surface temperatures rise, perhaps tens of seconds later.

This paper presents the results of an experimental investigation of the fuel-air mixing process in a port-fuel-injected, 4-valve, spark-ignited engine that was motored to simulate cold cranking and start-up conditions. An infrared fiber-optic instrumented spark plug probe was used to measure the local, crank angle resolved, fuel concentration in the vicinity of the spark gap of a single-cylinder research engine with a production head and fuel injector. The crank-angle resolved fuel concentrations were compared for various injection timings including open-intake-valve (OIV) and closed-intake-valve (CIV) injection, using federal certification gasoline. In addition, the effects of speed, intake manifold pressure, and injected fuel mass were examined.

Fuel transport was visualized within the cylinder of a port injected four-valve SI engine having a transparent cylinder liner. Measurements were made while motoring at 250 rpm to simulate cranking conditions prior to the first firing cycle, and at 750 rpm to examine the effects of engine speed. A production GM Quad-4 cylinder head was used, and the stock single-jet port fuel injector was used to inject indolene. A digital camera was used to capture back-lighted images of cylinder wall wetting for open and closed intake valve injection. In addition, two-dimensional planar imaging of Mie scattering from the indolene fuel droplets was used to characterize the fuel droplet distribution as a function of crank angle for open and closed intake valve injection. LDV was used to measure the droplet and air velocities near the intake valves during fuel induction. It was found that with open-valve injection a large fraction of the fuel impinged on the cylinder wall opposite the intake valves.

A reduced autoignition mechanism for iso-octane has been developed by identifying paths to formation of the stable species measured during motoring knock experiments and eliminating paths to formation of species that were not measured. The resulting mechanism includes low-, intermediate-, and high-temperature reactions and consists of 103 species and 131 reactions. This mechanism differs from detailed models not only in the number of reactions and species, but most importantly, in the nature and rates of the degenerate chain branching reactions. To implement this mechanism, a knock subroutine has been added to a quasidimensional spark ignition engine model that accounts for heat losses, blowby, etc. Thus, errors in the reactivity predictions can be assigned almost exclusively to the kinetics. Numerical predictions of the exhaust composition during motoring knock are compared with experimental measurements as a function of compression ratio for several operating conditions.

Because only the unburned gases in the crevices can contribute to hydrocarbon emissions, a model was developed that can be used to determine the temporal and spatial histories of both burned gas and unburned gas flow into and out of the piston-liner crevices. The burned fraction in the top-land is primarily a function of engine design. Burned gases continue to get packed into the inter-ring volume until well after the end of combustion and the unburned fuel returned to the chamber from this source depends upon both the position of the top ring end gap relative to the spark plug and of the relative positions of the end gaps of the compression rings with respect to each other. Because the rings rotate, and because the fuel that returns to the chamber from the inter-ring crevice dominates the sources between BDC and IVO when conditions are unfavorable to in-cylinder oxidation, these represent two sources of variability in the HC emissions.

In premixed turbulent combustion models, two mechanisms have been used to explain the increase in the flame speed due to the turbulence. The newer explanation considers the full range of turbulence scales which wrinkle the flame front so as to increase the flame front area and, thus, the flame propagation speed. The fractal combustion model is an example of this concept. The older mechanism assumes that turbulence enables the penetration of unburned mixtures across the flame front via entrainment into the burned mixture zone. The entrainment combustion or eddy burning model is an example of this mechanism. The results of experimental studies of combustion regimes and the flame structures in SI engines has confirmed that most combustion takes place at the wrinkled flame front with additional combustion taking place in the form of flame fingers or peninsulas.